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Oxidation of cyclohexanol, a six membered cyclic alcohol, by Ce(IV) is a slow-moving reaction. Therefore, it was investigated in a comparative study whether the oxidation rate can be increased by adding trace amounts of Ru(III) and Ir(III) metal catalysts in anionic (sodium dodecyl sulfate) and cationic (cetylpyridinium chloride) micellar media. The kinetics of the oxidation of cyclohexanol with Ce(IV) in acidic medium has been studied spectrophotometrically at 28°C under pseudo 1st order reaction condition. Based on the spectroscopic evidence the mechanisms for the reactions taking place in the presence of these metal catalysts were proposed.

Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media