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The composition and solubilization of the optimum microemulsion systems containing Triton X-100/pentan-1-ol/aliphatic hydrocarbon/water were studied with the ∊-β fishlike phase diagram method. The solubilities of the alkanol ( S  A ), the mass fractions of the alkanol in the interfacial layer ( A S  ) and the optimum solubilization parameters ( SP∗ ) of the microemulsion systems with different aqueous phases (salt, acid, alkali) and with different α values were obtained and discussed. The  SP ∗ values increase significantly with the cation radius of the chlorides (NaCl, KCl, CsCl), but decrease slightly with the anion radius of the sodium halides (NaCl, NaBr, NaI). However,  SP∗  values decrease with the increased salinities and NaOH contents. The trend was reversed for the acid systems. When the oil-water ratio (α) increases, the  S  A  and  A  S  values significantly increase, while the  SP∗  values increase slowly. As the length of the carbon chain of the alkane molecules increases, both the  S  A  and  A  S  values increase, while the  SP ∗ values decrease significantly.

Composition and Solubilization of the Microemulsion Systems Containing Triton X-100: Effects of Aqueous Composition and Oil-Water-Ratios