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Hydrotropes (amphiphiles) start to aggregate at a certain minimum concentration known as the minimum hydrotrope concentration (MHC), above which an appreciable solubilization of insoluble compounds in aqueous solution is observed. However, the MHC values are very high, thus, limiting the applications of hydrotropes. The salts are found to increase the association tendency of hydrotropes and reduction in the MHC. The present study discusses the effect of various electrolytes (Na + , Mg 2+  and K +  series) on the behavior of sodium salicylate at different temperatures. Design of experiment was employed to optimize the process parameters. Furthermore, thermodynamic parameters were investigated to observe the stability of the aggregates at higher temperatures.

Parametric Optimization and Thermo-dynamic Studies on the Influence of Electrolytes on Sodium Salicylate in Aqueous Solution