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A metal(II) ion (Cu 2+ )-induced vesicle phase was prepared from a mixture of n-undecylamine and CuCl 2  in aqueous solution. Cu 2+ -ligand coordination with n-undecylamine results in the formation of molecular bilayers because Cu 2+  can firmly bind to the amine groups of n-undecylamine which reduced the area of the head-group. In this system, no counterions in aqueous solution exist because of the Cu 2+ -ligand coordination, and the bilayer membranes are not shielded by salts. The vesicles were determined by transmission electron microscopy (TEM) images and dynamic light scattering (DLS) measurements.

The Micelle-to-Vesicle Phase Transition in Dilute Aqueous Solution from Undecylamine Induced by Metal(II) ion (Cu 2+ )