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The micelle solutions of sodium dodecyl sulphate (NaDS) modified by simultaneously presence of different aliphatic alcohols and an inorganic salt have been quantitatively characterized by the values of critical micelle concentrations, the degrees of counter-ion binding and electrostatic potentials of surface. The obtained characteristics of hybrid micelles and the coefficients of modifier distribution between aqueous solution and micellar pseudophase were used to develop a conceptual retention model in micellar liquid chromatography (MLC). The new retention model takes into account the microenvironment changes of an analyte when it goes from the hybrid micellar eluent to a modified surface of alkyl-bounded sorbent.

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The Quantitative Characterization of Chemical Modification of Sodium Dodecyl Sulphate Micellar Solutions and Retention Model in Micellar Liquid Chromatography