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^ Introduction -.^ Purpose and Scope 3 Description of Study Area 3 Previous Investigations 5 Methods ~^ Vapor-Diffusion Samplers 10 Ground-Water Sample Collection and Analysis 12 Borehole Geophysics 13 Microcosm Investigation of Vinyl Chloride Degradation 13 Transport of Ground-Water Contamination 14 Discharge of Contaminated Ground Water to Little Rocky Creek 14 Major Pathways of Subsurface-Contaminant Transport 18 Geochemical Tracers of Contaminant Transport 18 Fracture-Trace Analysis 23 Transformations of Ground-Water Contamination 30 Distribution of Terminal Electron-Accepting Processes 30 Field Evidence for Chlorinated Volatile Organic Compound Dechlorination 31 Laboratory Evidence for Vinyl Chloride Depletion 40 Summary ^ References ^ Appendix I. Vertical Flow Measured With a Heat-Pulse Flowmeter in Selected Wells, Greenville, S.C., May 10 to 13, 1994 49 Appendix II. Plots of Downhole Geophysical Logs Obtained From Selected Wells, Greenville, S.C ^ Appendix III. Reflectors Identified by Single-Hole Borehole-Radar Surveys, Greenville, S.C., July 26 Through August 2, 1994 71

water-resources investigations report

Transport and transformations of chlorinated-solvent contamination in a saprolite and fractured rock aquifer near a former wastewater-treatment plant, Greenville, South Carolina