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Cl Introduction 1 Tectonic History 2 Thermal History 2 Stratigraphy 2 Previous Work on the Illitization Reaction 4 Mineralogy of Illite-Smectite  5 Illitization in Contact Metamorphic Environments 5 Materials and Methods  7 Sample Acquisition and Preparation  7 Clay-Mineral Analysis 7 X-Ray Fluorescence Spectrometry 8 Scanning Electron Microscopy 8 Petrographic Thin-Section Examination  8 Vitrinite Reflectance 8 Results 8 Petrography of Igneous Rocks 8 Diagenesis of Sedimentary Rocks 9 Clay-Mineral Composition 9 Variation in Illite-Smectite Expandability 9 Variation in Other Clay Minerals 10 Variation in Vitrinite Reflectance 11 Heat-Flow Calculations 11 Discussion 22 Reaction Kinetics 22 Factors Affecting Illitization Reaction Rates  25 Calculations of the Extent of the Illitization Reaction  25 Conduction, Diffusion, and Advection Near Intrusions 29 Paragenesis of Other Minerals 29 Summary and Conclusions 34 References Cited 34 Appendix 37

Thermal effects of thin igneous intrusions on diagenetic reactions in a Tertiary basin of southwestern Washington