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The aim ofourimrestigation was to evaluate the influence ofsofl depth, soil moisture, and herbicide concentration on the persistence and d^radadon of metolachlor in soil. Metolachlor was more persistent in subsur&ce soOs than surface soil regardless of soil moisture or herbidde concentration. Greater quantities ofbound residues and extractable degradation products were found in the sur&ce soOs as a result of the increased soil sorption, and miaobial activity associated with soil containing more organic matter. Saturated soil favored degradation and the formation of bound residues compared to unsaturated soil. A significantly smaller percent of the applied metolachlor was bound to the soil or degraded in the sofl of the 90-^g,'g treated soil compared to the 9-^g/g treated soil. The reduction in degradation in the subsur&ce soils and the 90-|ag/g treated soil suggests metolachlor residues that leach to subsur^ce soil or large concentrations of metolachlor have a greater potential to contaminate surface water and groundwater as a result of their increased perastence and mobility.

The persistence, degradation, and mobility of metolachlor in soil and the fate of metolachlor and atrazine in surface water, surface water/sediment, and surface water/aquatic plant systems