English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

Our group previously developed the synthesis of main group Zn(II) and Mg(II) complexes supported by the To (tris(4,4-dimethyl-2-oxazolinyl)phenylborate) ligand. The reactivity of these main group oxazolinyl based complexes in oxygenation, hydrosilylation, and hydroboration reactions provided motivation for studying the reactivity of late first-row transition metals. This thesis focuses on the synthesis, characterization, and reactivity of late transition metal complexes based on iron, nickel and cobalt containing To as the ancillary as well as the synthesis and characterization of other paramagnetic molecules . Salt metathesis reaction of TlTo with CoCl2THF (THF = tetrahydrofuran), FeBr2, or NiCl2DME (DME = dimethoxyethane) at room temperature in THF afforded ToCoCl, ToFeBr, and ToNiCl, respectively. ToCoCl, ToFeBr, and ToNiCl react with NaOAc to form the acetate complexes ToCoOAc, ToFeOAc, and ToNiOAc, respectively. ToCoOAc was studied in the oxidation of cyclohexane using meta-chloroperoxybenzoic acid (mCPBA) as the oxidant and found to selectively catalyze the formation of cyclohexanol over the overoxidized products of cyclohexanone and ε–caprolactone. Reaction of ToCoCl, ToFeBr, and ToNiCl with alkyllithiums or potassium benzyl were attempted as a route to organometallic complexes. The nickel(II) alkyls were not identified under the reaction conditions attempted; however, ToCoR (R = Me, Et, Bu, CH2SiMe3, Bn, and Ph) and ToFeR (R = Bn) compounds were found to be isolable. ToCoR (R = Me, Et, Bu, CH2SiMe3, Bn, and Ph) complexes react with CO followed by O2 to form the carboxylate compounds ToCoO2CR (R = Me, Et, Bu, CH2SiMe3, Bn, and Ph). The direct insertion of CO2 into the Co-R bond is determined to be much slower, requiring several days to weeks depending upon the R group. ToFeBn reacts with CO to form

Synthesis and reactivity of paramagnetic late transition metal complexes supported by tris(oxazolinyl)phenylborate