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An attempt was made to enhance the oxygen evolution efficiency in seawater electrolysis by the addition of tin, antimony and molybdenum to Mn-W oxide electrocatalysts prepared by anodic deposition on the intermediate Ir 1-x-y Sn y O 2+0.5y /Ti electrode. Ir 1-x-y Sn y O 2+0.5y /Ti supported nanocrystalline γ-MnO 2 type Mn-W-X-O(X=Sn,Sb,Mo) electrocatalysts with grain size of about 5-11 nm were tailored by anodic deposition. All the examined Mn-W-X(X=Sn,Sb,Mo)- O anodes showed the almost 100% oxygen evolution efficiency at 1000 A.m -2 in 0.5 M NaCl solution of pH 1 at 25°C. They guaranteed the stable anode performance of about 99.75-99.85% oxygen evolution efficiencies for more than five months. Keywords : Global warming; CO 2 recycling; Oxygen evolution anode; Seawater electrolysis; Hydrogen production electrode. DOI: 10.3126/sw.v8i8.3844 Scientific World Vol.8(8) 2010 pp.39-43

vaijñānika jagat

Effects of Tin, Antimony and Molybdenum in Mn-W-O /Ir&lt;sub&gt;1-x-y&lt;/sub&gt;Sn&lt;sub&gt;y&lt;/sub&gt;O&lt;sub&gt;2+0.5y&lt;/sub&gt;/Ti Anodes for Oxygen Evolution in Seawater Electrolysis