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In the present paper we performed the analysis of available data onstructural, thermodynamic and mechanical properties of B6O. Although thecompound is known for half a century and has been extensively studied, manyproperties of this boron-rich solid remain unknown or doubtful. Semi-empiricalanalysis of our experimental and literature data allowed us to choose the bestvalues of main thermodynamic and mechanical characteristics among previouslyreported data, to predict the thermoelastic equation of state of B6O, anddependence of its hardness on non-stoichiometry and temperature.

Experimental study and critical review of structural, thermodynamic and mechanical properties of superhard refractory boron suboxide, B6O