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The effects of pH, NOM concentration ,fractionsand the chlorine dose on the f ormation and speciation of THMs and HAAswere determined in Altinapa Dam water (Konya/Turkey).Water sample was isolatedand chlorinatedat differentTOC levelsand pHs.The isolate wasfractioned; THM and HAA species were measured after chlorination.THM increasedwith i ncreasing pH (6to8) whereas a consistentpH tendency could not be inferred from the HAA changes. CF is the dominant THM specie which exerts up to 91% of the total THM. The majority of total HAAs composed of MCAA, DCAA and TCAA .The hydrophobic fraction w as the main THM precursor under the studied conditions although their percentage was lower than hydrophilics, whereas, hydrophilic fraction had significant contributio n to HAA formation, in contrast to the general tendency for HAA.High correlation (0.97)was calculated between total THMs and HAAs.

DBP formation and speciation in a central anatolian dam water depending on pH, TOC level, fraction and chlorine dose