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In this study, a cellular automaton model for the oxidation of binary alloys is proposed, by treating internal and external oxidation separately and simultaneously. As an example, the oxidation of nickel-chromium alloys with the formation of spinel and the doping effect is simulated. The oxidation rate and the micro-morphology of simulation are compared with experimental results of others to verify the reliability of the model. The influences of alloy content, reaction temperature and interdiffusion velocity of alloys on the oxidation rate are forecast. Furthermore, the model is capable to simulate the oxidation in oxidants other than oxygen.

Cellular Automaton Simulation for the Oxidation of Binary Alloys