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The addition of another electrochromic component has been considered to be an important way to obtain multicolor film. Herein, we fabricated the composite films containing polyoxometalate (POM) clusters, auxiliary materials and polyelectrolyte on quartz and FTO substrates by layer-by-layer assemble method (LbL). The composite film shows high optical contrast, suitable response time and low operation potential. The interesting feature of the electrochromic film is its adjustable color by reduction of polyoxometalate at different potentials. The results provide valuable information for exploring application in tunable-color electrochromic devices.

Electrochromic Composite Films of Tunable Color based on Polyoxometalate and Auxiliary Materials