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. A photochromic diarylethene 1, 2-bis-[2-methyl-5-(3-pentyl) phenyl-3-thienyl] perfluorocyclopentene was synthesized and characterized. Its properties, such as photochromism and fluorescence were investigated systematically. Upon irradiation with UV light, it underwent a reversible transformation from the open-ring isomer to the closed-ring isomer. The kinetic experiments showed that the cyclization and cycloreversion processes were zeroth and first order reaction. This new photochromic system also exhibited fluorescence switching in hexane solution.

Synthesis and Application of 1,2-bis-[2-methyl-5-(3-pentyl)phenyl-3-thienyl]perfluorocyclopentene