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In this paper we present many new families of identities for multiple harmonic sums using binomial coefficients. Some of these generalize a few recent results of Hessami Pilehrood et al. As applications we prove several conjectures involving multiple zeta star values (MZSV): the Two-one formula conjectured by Ohno and Zudilin, and a few conjectures of Imatomi et al. involving 2-3-2-1 type MZSV, where 2 means some finite string of 2's

Identity families of multiple harmonic sums and multiple zeta star values