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Modified films were prepared by deposition of poli-[(H2O)(L)2Ru-O-Ru(L)2(OH2)]4+ (L=4-methyl- 4´-pyrrol-1-yl-buthyl-2,2´-bipyridine) (poly-dim.), on felt carbon electrodes, by direct anodic electropolymerization of the monomer. The electrocatalyst activity of these modified carbon felt carbon electrodes was tested in alcohols oxidations, at constant potential +1.15 V (vs SCE), in 1.0 and 6.8 pH. The started alcohols and the products were: benzyl alcohol (benzaldehyde), cycloexanol (cyclohexanone), 1-phenylethanol (acetophenone) and p-methoxybenzyl alcohol (p-methoxybenzaldehyde). The reactions showed very selectivity, and good yields were observed to the products.

Eletrodos de feltro de carbono modificados com filme dimérico de rutênio: aplicação em oxidações eletroquímicas de álcoois