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Проведен расчет температур плавления и кристаллизации и построена фазовая диаграмма металлических частиц системы Pd - Pt размером 10 нм. Поверхностная и межфазная энергии, их температурные и размерные зависимости оценивались модифицированным электронно-статистическим методом. Установлено, что вид фазовой диаграммы для наночастиц Pd - Pt имеет существенные отличия от диаграммы объемных фаз, включая гистерезис плавления-кристаллизации. The melting and crystallization temperatures have been calculated and the phase diagram of Pd - Pt metal particles of 10 nm in size has been constructed. The surface and interfacial energies, their temperature and size dependences were estimated by a modified electron-statistical method. It was found that the form of the phase diagram for Pd - Pt nanoparticles has significant differences from the diagram of bulk phases, including the melting-crystallization hysteresis.

THE INFLUENCE OF SURFACE INTERPHASE CHARACTERISTICS ON THE BEHAVIOR OF THE PHASE DIAGRAM OF NANOPARTICLES OF THE PALADIUM-PLATINUM ALLOY