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X-ray absorption fine structure (XAFS) at the K-edge of copper has been studied in some cobalt (II) mixed ligand complexes having Schiff base and 3 hydroxy Picolinamide ligands. The study can be used to yield useful and important information about the molecular structure of the complexes. The X-ray absorption measurements have been performed at BL-8 Dispersive EXAFS beamline at 2⋅5 GeV Indus-2 Synchrotron Source at RRCAT, Indore, India. The data obtained has been processed using EXAFS data analysis program Athena. From the experimental measurements, the energies of the K absorption edge, chemical shifts, edge-widths, shifts of the principal absorption maximum in the complexes have been estimated. The data obtained from these studies have been utilized to estimate effective nuclear charge and percentage covalency.

international journal of scientific research in physics and applied sciences

Near edge K-Shell X-ray absorption fine structure (NEXAFS) Analysis of Co (II) Mixed Ligand Complexes with Schiff base and 3-hydroxy Picolinamide Ligands