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This work points out the importance of the substrate boundary conditions to lower the dissipation in the dynamic measurement and access the closest dynamic characteristics of liquids, in particular to access the low frequency shear elasticity. The liquid/surface interface is a source of dissipation that enters and impacts the measurement. Examples of steady-state shear flows or flow birefringence are presented to highlight the non-universality of the behavior with respect to the nature of the substrate or the sheared thickness. Additionally the present development completes and extends the identification of low frequency shear elasticity made at sub-millimeter gaps in various one-component liquids to salt-free aqueous solutions (CTAB-water (Hexadecyl-TrimethylAmmonium Bromide))

oil and gas science and technology

Importance of Interfacial Interactions to Access Shear Elasticity of Liquids and Understand Flow Induced Birefringence from Liquid Crystals to Worm-Like Micellar Solutions