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ion pathways are likely thermodynamically controlled because the barriers for the H abstraction reactions by HO· are normally either very low or even submerged below the reactants. The H abstraction by HO· should be exothermic since the strength of the O-H bond formed, 117.6 kcal·mol, is higher than the strength of C-H bonds broken. In the case of the thermodynamic control, the relative yields of the radicals discussed above is determined by their relative energies and hence should be identical to the relative yields evaluated for the H homolytic bond dissociation. 3.4.6.2.2 Fragmentation of Carbon Centered Radicals The carbon centered radicals produced by hydroxyl radical mediated hydrogen abstraction can undergo β-scission or react with O2 to produce peroxyl radicals. The unimolecular fragmentation channels for each of the carbon centered were calculated to

Fundamental Mechanistic Studies on the Ultrasonic Treatment of Problematic Water Pollutants and Toxins