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Third-party users may view, print, copy and download the content for personal use or academic purposes. Users may also post links to the published WIT Press version of the Work, including the Digital Object Identifier (DOI), for their own non-commercial use. All third-party users must provide complete attribution to both the WIT Press publication title and the names of the author(s) of the Work. To copy otherwise, or to distribute the Work by third parties, requires the permission of WIT Press.Using the DLVO (Derjaguin, Landau, Verwey, Overbeek) theory, which accounts for quantum mechanics and electrostatics at the macroscopic level, the thermodynamic expressions for (thermodynamic) equilibrium contact angles of drops on solid substrates and menisci in solid wall capillaries are, operationally and unambiguously, expressed in terms of the corresponding Derjaguin pressure.\udThe latter’s S-shape is responsible for microdrops and other phenomena appearing on flat solid substrates

Surface forces and wetting features in drops and capillaries