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Structural effects of nitro-substituted amineimide derivatives on photobase generation were investigated by using an epoxide/thiol curing system. The absorption of amineimide derivatives was closely related to the position of a nitro group and the efficiency of photobase generation increased in the order of para>meta>ortho position. The molecular size of the amines generated from amineimide derivatives was found to affect the curing temperature of an epoxide/thiol curing system: The smaller the molecular size, the lower the curing temperature at higher concentration.

Structural Effects of Nitro-substituted Amineimide Derivatives on the Photobase Generation in an Epoxide/thiol Curing System.