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groups as photobase generators, which generate primary amines. Although photobase generators which generate tertiary amines are very interesting from the viewpoint of practical use, papers on them are very few. Neckers et al. reported that a quaternary ammonium borate acts as a photobase generator to generate tertiary amines. [5,6] Although we have also reported that quaternary ammonium salts having a dithiocarbamate anion act as photobase generators [7], details of their photolysis were not clarified. In this paper, we report the mechanism of photolysis of quaternary ammonium dithiocarbamates and their use as photobase generators. 2. EXPERIMENTAL Preparation of QA salts Quaternary ammonium bromide (QA salt I-Br) and quaternary ammonium N,N-dimethyldithiocarbamate (QA salt I-S) were

Photolysis of Quaternary Ammonium Dithiocarbamates and Their Use as Photobase Generators.