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Synthesis of a new bridging ligand 4ʹ-{4-[(2,2ʹ-bipyridin)-4-yl]-phenyl}-2,2ʹ:6ʹ-2ʹʹ-terpyridine (I) was reported. A Suzuki cross-coupling reaction was conducted for the preparation of such ligand in two different routes either between 4ʹ-(4-bromophenyl)-2,2ʹ:6ʹ-2ʹʹ-terpyridine and 2,2ʹ-bipyridyl-4-boronic acid or 4ʹ-(4-boronatophenyl)2,2ʹ:6ʹ,2ʹʹ-terpyridine and 4-bromo-2,2ʹ-bipyridine.

Synthesis and characterization of a new ditopic bipyridine-terpyridine bridging ligand using a Suzuki cross-coupling reaction