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Received 04-08-2017 Accepted 06-12-2017 Published on line 07-09-2017 Dates to be inserted by editorial office Abstract An efficient and simple synthetic protocol has been developed for preparation of [1,2,5]chacogenadiazolo[3',4':5,6]pyrazino[2,3-f][1,10]phenanthrolines. The first Re(I) bromotricarbonyl complex bearing [1,2,5]oxadiazolo[3',4':5,6]pyrazino[2,3-f][1,10]phenanthroline as a ligand was synthesized. Crystal structure of complex and free ligand, photoand electroluminescent properties of facbromotricarbonyl ([1,2,5]oxadiazolo[3',4':5,6]pyrazino[2,3-f][1,10]phenanthroline)rhenium (I) were investigated.

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Synthesis, crystal structure and electroluminescent properties of fac-bromotricarbonyl ([1,2,5]oxadiazolo[3',4':5,6]pyrazino- [2,3-f][1,10]phenanthroline) rhenium (I)