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The synthesis of three chiral tertiary amides by ring opening of the symmetric 1,3-imidazolidine 2 under mild conditions is described. 1H NMR dynamics studies were performed to identify three rotamers present in solution, which were also examined by DFT calculations.

Synthesis and conformational analysis of novel tertiary amides derived from N-[(S)-α-phenylethyl]-1,3-imidazolidine