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Contribution to Availability Assessment of Complex Systems with one Shot Items  As we use complex systems with one shot items in many technical applications we need to know basic characteristics of such a system. Performance, safety and others are as much important as dependability measures. As the one shot item is supposed to back up the main system function the total reliability of the system should be higher then. The paper will present a theoretical approach to determining the complex system task/mission success probability rather than a theoretical approach to determining the dynamic reliability (operational availability), and then a practical example.