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Fig. 15. Survey spectra of AuC6H4CH2Br, AuC6H4CH2SCSNEt2, and Au–PHEMA (obtained by surface-initiated iniferter). AuC6H4CH2Br is prone to displacement of aryl groups by dithiocarbamate due to a favourable reaction between the latter and gold. If displacement is only partial, iniferter is successful as PHEMA is grafted (Au–PHEMA) as proved by high resolution C 1s feature. Conditions: AuC6H4CH2Br was prepared according to Mahouche et al. (2009) then allowed to react in 10 mL anhydrous tetrahydrofurane with 1.02 g (6 mmol) of Et2NCS2Na at r.t. for 3 h. SIPP was conducted in chloroform flushed with nitrogen under conditions similar to those reported by Gam-Derouich et al. (2010a).

chemical papers

Erratum to: “Zakaria Salmi, Sarra Gam-Derouich, Samia Mahouche-Chergui, Mireille Turmine, Mohamed M. Chehimi: On the interfacial chemistry of aryl diazonium compounds in polymer science”