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Phase relations up to the solidus line in part of the Sb-Zn-O system have been investigated over the entire concentration range of the α-Sb2O4-ZnO system in air ( \( P_{O_2 } \) = 0.21 atm) using XRD and DTA/TG. The components of this system in air form ZnSb2O6 and Zn7Sb2O12. The results allow division of the system into three subsystems, i.e. α-Sb2O4-ZnSb2O6; ZnSb2O6Zn7Sb2O12 and Zn7Sb2O12-ZnO. The temperature ranges over which the ZnSb2O6 and Zn7Sb2O12 remain at equilibrium with other solid compounds depend on the gaseous atmosphere.

Phase relations up to the solidus line in the part of the Sb-Zn-O system