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An innovative hydrogen measuring method applicable to high temperature systems such as oil refinery plants is presented. The electrochemical measurements of permeability., diffusivity and content of hydrogen permeated through a plain carbon steel at 823K were made by using a proton conductive solid electrolyte (5mol% Yb2O3-SrCeO3). A space was introduced between steel and filler metal in order to improve the accuracy of measurements. As a result, it was substantiated that molecular hydrogen produced during diffusion in steel can be measured with high accuracy for a longer period in comparison with the previous method.

Innovative Electrochemical Measuring Method of Hydrogen Permeated through Steel at High Temperature Using Solid Electrolyte.