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Eleven weak absorption peaks of Fe3+ and two broad absorptions of Cr3+ doped in synthetic yttrium-aluminium-garnets, Y3Al2Al3O12, have been assigned to d-d transitions of the metal ions in octahedral and tetrahedral sites. All of these absorption peaks have 1:1 correspondence to transitions which are predicted to occur in lower energy region by energy level dia grams. Intensity analysis of Y3Al2Al3O12: Fe (III) spectra reveals that the ratio of site occupancy of Fe3+ between octahedral and tetrahedral positions is approximately 100:

Optical absorption spectra of iron (III) and chromium (III) doped in synthetic yttrium-aluminium-garnets (YAG)