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In this work we describe the synthesis and characterization of new Mannich bases derived from 2-phenylaminothiazole, by applying the trimolecular condensation of thiazole aldehydes with aniline and acetone, catalyzed by lipase B from Candida antarctica. The target compounds were obtained with 68-76% yields, in mild and eco-friendly reaction conditions. The new heterocyclic Mannich bases were characterized by melting points, 1H NMR, 13C NMR and MS spectrometry.

Heterocycles 50. Synthesis and characterization of new 2-phenylaminothiazole derived Mannich bases by biocatalytic multicomponent reactions