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The influence of immobilized catalytic compositions, obtained by immobilizatio n of cyanide complexes of transition metals: Ni, Pd, Pt, Со, Fe, Ru, and oxysalts of vanadium on the aluminum oxide as a carrier, on the initial stages of the liquid-phase oxidation reaction of 1-octene by the molecular oxygen was studied. It was established that the highest activity in the oxidation reaction of 1-octene by the molecular oxygen showed the catalytic composition containing immobilized ruthenium cyanide complex K2(Ru(CN)6)-MnCl2·4H2O ( XI) whereas the activity of catalytic composition containing immobilized nicole cyanide complex K 2 (Ni(CN)4)- VO(SO4)·3H2O (I) was the lowest one.

Oxidation of 1-Octene by the Molecular Oxygen in the Presence of Immobilized Catalytic Compositions