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Glycerolysis of rapeseed oil over several solid bases using fixed bed flow reactor has been studied. It was found that Mg-Al hydrotalcite and Al2O3 supported CaO- ZnO demonstrate high activity in this reaction. The yield of monoglycerides reaches 70 % with 96 % oil conversion at 513 K. It was shown that pores size of a catalyst is an important factor of intensificati on of the glycerolysis process. It was found that turpentine additive decreases the reaction temperature due to higher solubility of glycerol in oil.

Study of a Continuous Process of Glycerolysis of Rapeseed Oil with the Solid Base Catalysts