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Anomalies were obsd. in measurements of emf. and elec. cond. measurements of solid oxide electrolyte cells involving Cr(s)-Cr2O3(s) electrodes.  Transformation in the system at ∼1653 K explains the anomalies mentioned above on the basis of measured temp. dependence of emf. and total and electronic conductivities of the cells

Some evidences on the instability of Cr-Cr2O3 electrode in the electrochemical oxygen sensors at steelmaking temperatures.