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Titanium addition to steel creates various forms of non-metallic inclusions such as oxide, nitride, carbide, and sulphide, depending on the steel composition. The effect of these non-metallic inclusions to microstructure and mechanical properties of solid steel is quite important to understand to produce steel with desired properties.1) Moreover, TiOx inclusions easily get agglomerate and forms clusters by decreasing the final steel properties and causes a severe submerged entry nozzle clogging problem during continuous casting of Ti-bearing steel. To understand this phenomenon thoroughly, accurate knowledge on thermodynamics and phase equilibria in the Al–Ti–O and Fe–Al–Ti–O system is crucial. The present author (Jung et al.2)) already performed the comprehensive critical evaluation and optimization of the Al–Ti–O (Al2O3–Ti2O3–TiO2) system and presented the inclusion stability diagram of the Fe–Al–Ti–O system for better understanding the inclusion chemistry in Ti-bearing and Al-killed steel. In the previous study, Al2TiO5 and Ti3O5 were treated as separate stoichiometric phases. However, it is found out that both solid phases belong to pseudobrookite solid solution, which will be discussed later. Coupled Experimental Study and Thermodynamic Modeling of the Al2O3–Ti2O3–TiO2 System

isij international

Coupled Experimental Study and Thermodynamic Modeling of the Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;–Ti&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;–TiO&lt;sub&gt;2&lt;/sub&gt; System