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Steel slags is the largest solid waste during steel-making process. About 0.2 billion tons of steel-slag in 2017 were discharged with output of 1.69 billion crude steel in the world.1) Due to low cementitious reactivity and instability, steel slags was mainly reused as low value-added raw materials in areas, such as concrete, road pavement, water way construction and artificial reefs areas. Improve its values in utilization process became new trends.2) Many new methods such as converting it into glass ceramics,3) building ceramics,4) fertilizes,5) special backfill materials6) and recovery of phosphorus7) were explored. Porous permeable materials, which have open pores and channels, are in huge demand for municipal construction because of their many special properties, such as water permeability and sound absorption.8,9) Permeable pavement is an essential component in construction of a sponge city.10,11) Permeable pavement allows rainwater to penetrate through to the soil, and the filtered rainwater is then either harvested for later reuse or released slowly into the underlying soil or drainage system. Utilization of steel slag in permeable pavement materials could be a potential high value-added Mechanism of Pore Formation in Novel Porous Permeable Ceramics Prepared from Steel Slag and Bauxite Tailings