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Pre-painted hot-dip 55 mass% Al–Zn alloy coated (galvalume) steels are widely used as architectural and automotive materials due to their high weatherability in atmospheric environments. The high durability of pre-painted galvalume steels is derived from the sacrificial protection of steel by the Al–Zn coating layer, and anti-corrosive pigments are added to the primer layers to improve the delamination of the organic paint. Strontium chromate (SrCrO4) is typical of such anti-corrosive pigments, and effective against filiform corrosion on pre-painted steels at cut edges and coating defects.1–4) However, due to concerns regarding the toxicity of chromium (VI)-containing compounds, the use of SrCrO4 has been restricted,5) and the search for an alternative to chromate base pigments has been extensive.1,6–14) Phosphate pigments are traditional and promising alterEffect of Phosphate and Chromate Pigments on Sacrificial Corrosion Protection by Al–Zn Coating and Delamination Mechanism of Pre-painted Galvalume Steel

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Effect of Phosphate and Chromate Pigments on Sacrificial Corrosion Protection by Al–Zn Coating and Delamination Mechanism of Pre-painted Galvalume Steel