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Rare earth (RE) elements are expected to be effective deoxidizing agents in steelmaking because of their strong affinity for oxygen. Deoxidation products would be composed of the CaO-AlO1.5-REOx system with the existence of secondary refining fluxes and/or in case of complex deoxidation with Ca and Al. This study focuses on Cerium (Ce), which is one of the main components in the misch metal alloys. The phase relations for the CaO-AlO1.5-CeO1.5 system have been investigated at 1823 K and 1873 K by chemical equilibration technique also by clarifying the existence of ternary intermediate compounds, CaO·AlO1.5·CeO1.5 and CaO·3AlO1.5·CeO1.5. Also, by clarifying the activity of AlO1.5 of the present system, Al-Ce complex deoxidation behavior is discussed.

Thermodynamic Properties of the CaO–AlO<sub>1.5</sub>–CeO<sub>1.5</sub> System