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1) Department of Chemistry, Faculty of Sciences, Kyushu University, Higashi-ku, Fukuoka, 812-8581 Japan. 2) Kansai Research Center, Forestry and Forest Products Research Institute, 68 Nagaikyutaroh, Momoyama, Fushimi, Kyoto, 612-0855 Japan. 3) Akiyoshi-dai Museum of Natural History, Akiyoshi, Shuhocho, Mine, Yamaguchi, 754-0511 Japan. 4) Naganobori Copper-mine and Culture Center, Naganobori, Mitohcho, Mine, Yamaguchi, 754-0213 Japan. 5) Departments of Earth Science, Graduate School of Science, Tohoku University, Aoba, Aramaki, Aoba-ku, Sendai, 980-8578 Japan. 6) Department of Earth Environmental Sciences, Graduate School of Science and Technology, Kumamoto University, Cyuou-ku, Kumamoto, 860-8555 Japan.

Sulfide Ore Smelting at the Naganobori Copper Mine Recorded on Speleothems from the Ogiri No. 4 Pit on the Akiyoshi-dai Plateau, Yamaguchi, Japan