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Effect of the outer fraction of dialyzed water extract of bigeye tuna meat on NaCl-catalyzed oxidation of linaleate was examined using model system. Oxidation of linoleate was carried out at 25°C and Aw 0.84 and followed by determinations of remaining linoleate and POV. Linoleate oxidation was markedly inhibited by meat fraction which is diffusive through a cellophane membrane, adsorptive on cation exchange resin, and soluble in 80% EtOH. The inhibitory effect of the meat fraction on linoleate oxidation depended upon the concentration but not the pH. Furthermore, HCl-hydrolysis of the meat fraction resulted in loss of inhibitory effect on linoleate oxidation. From these results, amino acids and/or small molecular peptides such as anserine were considered to participate in the inhibitory effect of bigeye tuna meat extract on NaCl-catalyzed oxidation of linoleate.

Inhibitory effect of bigeye tuna meat extract on sodium chloride-catalyzed oxidation of linoleate.