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The co-telomers containing peroxide linkages on the side chain and chlorine atom on its chain ends, were synthesized by the radical co-telomerization of styrene and methacryroyl-oxyethyl-t-butylperoxycarbonate with carbon tetrachloride as a telogen. The molecular weight and the concentration of active oxygen of the co-telomers could be controlled by regulating the fraction of co-monomers and telogen. These co-telomers were able to proceed the rapid vulcanizatin reaction of SBR under ordinal conditions and the tensile properties of vulcanizates showed higher value than one with dicumyl-peroxide. It is thought that the co-telomers acts as not only the radical generator but also the co-vulcanization agent.

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IMPROVEMENT IN PROPERTIES OF RUBBER WITH OLIGOMER CONTAINING PEROXIDE LINKAGE (I) SYNTHESIS OF CO-TELOMER CONTAINING PEROXIDE LINKAGE ON SIDE CHAIN AND VULCANIZATION OF STYRENE-BUTADIENE RUBBER