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interface in Fe:Cr diffusion couples is not equal to the equilibrium value even if the coupies are heated for a long time more than 100 hr. In a diffusion experiment Eifert et al.(2) reported a systematic deviation from the equilibrium composition at the bcclfcc interface in Cu:Al diffusion couples. Such deviations have also been detected in the two-phase diffusion couples of Au:Co by Braun et al.(3) and those of Ni:Cr by the present authors(4). Furthermore, Oikawa et al.(5) suggested the occurrence of a deviation in carbon concentra-

transactions of the japan institute of metals

Phenomenological Consideration on the Compositional Deviation from Equilibrium at the &lt;I&gt;bcc&lt;/I&gt;&amp;frasl;&lt;I&gt;fcc&lt;/I&gt; Interface in Fe: Cr Diffusion Couples