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Bond order (B0) and metal d orbital energy level (Md) values were calculated for our recently developed Ti­(6,7)Cr­3Sn and Cr substituted Ti­(6,7)Ag­3Sn alloys developed in this study. Position of these alloys in the B0-Md phase stability map developed by Morinaga and co-workers was then determined. Phase constitution, mechanical and shape memory properties were co-related with the position of Ti­(6,7)Cr­3Sn and Cr substituted Ti­(6,7)Ag­3Sn alloy in the B0-Md phase stability map. Cr substitution with Ag has resulted drastic decrease in the bond order (B0) and metal d orbital energy level (Md) values, resulting drastic decrease in the strength, fracture strain and shape memory properties. Position of Ti­(6,7)Cr­3Sn alloys was within the twinning region of B0-Md phase stability map and these alloys exhibited good mechanical and shape memory properties due to stress induced martensitic transformation. It is concluded that position of developed Ti­Cr­Sn and Ti­Ag­Sn alloys in the B0-Md phase stability map not only affect the phase constitution but also the mechanical and shape memory properties.

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Comparison of Bond Order, Metal d Orbital Energy Level, Mechanical and Shape Memory Properties of Ti&amp;ndash;Cr&amp;ndash;Sn and Ti&amp;ndash;Ag&amp;ndash;Sn Alloys