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Electrodeposition was performed in an unagitated solution from a urea-based melt bath containing Co and La under galvanostatic (10­ 40mA·cm12) and coulostatic (10C·cm12) conditions at 403K, and the structure of the deposits was investigated. Co deposited in a metallic state at 10mA·cm12, whereas it was incorporated into deposits mainly as an oxide at high current densities of 30 and 40mA·cm12. La codeposited with Co as an oxide irrespective of current density. The content of La2O3 increased with current density. The deposits showed a granular crystal structure and became nonuniform crystals comprising large localized granules at high current densities. [doi:10.2320/matertrans.M2011379]

Structure of Deposits Obtained from Urea-Based Melt Bath Containing Co and La