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mechanism of fayalite scale, which can form as a ‘‘sub-scale’’ in Si containing steels. The diffusion coefficient of oxygen in the oxide layer, DO, and the oxygen concentration at specimen surface, NO (s) , which are constituents of the internal oxidation rate constant, (2DONO (s) =NB (O) n), were calculated under various oxidation conditions, and the rate equation for the internal oxide layer was derived. Comparing the calculated and the measured values of (2DONO (s) =NB (O) n), we confirmed that the rate equation determined for the internal oxide layer was reasonable. The conditions at the boundary between internal to external oxidation of Si containing steels (Fe-Si alloys) at 850  C were also calculated by substituting the calculated values of DO and NO (s) at the boundary into the rate equation. [doi:10.2320/matertrans.M2009256]

Calculations of Internal Oxidation Rate Equations and Boundary Conditions between Internal and External Oxidation in Silicon Containing Steels