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Effect of Nb addition on the stabilization of amorphous Fe80B20 alloy was studied by electron diffraction structure analysis with the help of computer simulation. Atomic structure models with dense-random-packing 5000 atoms were constructed to reproduce interference functions obtained experimentally for the amorphous Fe80B20 and Fe70Nb10B20 alloys. In the structure models so obtained, prism-type local atomic arrangements dominated around B atoms in both the alloys, while deformed-bcc and icosahedral-like clusters were frequently found around Fe atoms. The icosahedral-like clusters and short Fe–Fe bondings were more frequently found in Fe70Nb10B20. The difference of glass forming abilities of these alloys is discussed in relation to the local structural differences.

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Local Atomic Structures of Amorphous Fe&lt;SUB&gt;80&lt;/SUB&gt;B&lt;SUB&gt;20&lt;/SUB&gt; and Fe&lt;SUB&gt;70&lt;/SUB&gt;Nb&lt;SUB&gt;10&lt;/SUB&gt;B&lt;SUB&gt;20&lt;/SUB&gt; Alloys Studied by Electron Diffraction