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Phase transformation behavior in Fe 7 7 Nd 4 . 5 B 1 8 . 5 metallic glass during electron irradiation and thermal annealing was investigated. Crystallization from glassy phase during thermal annealing occurred in multi-stages forming α-Fe and several intermetallic compounds. Electron irradiation induced crystallization occurred at 298K and nanostructure composed of α-Fe, Nd 2 Fe 1 4 B and Fe 1 7 B 2 precipitates embedded in amorphous matrix was formed. The electron irradiation induced crystallization behavior was discussed by atomic displacement due to electron knock-on effect and atomic diffusion via free volume in amorphous phase.

materials transactions

Electron Irradiation Induced Nano-Crystallization in Fe&lt;SUB&gt;77&lt;/SUB&gt;Nd&lt;SUB&gt;4.5&lt;/SUB&gt;B&lt;SUB&gt;18.5&lt;/SUB&gt; Metallic Glass