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The new Cu-based bulk glassy alloys in Cu–Zr–Ti–Sn–Si alloy system were formed by copper mold casting. The critical diameter for glass formation is 5 mm for Cu50Zr42:5Ti7:5, and increases to 6 mm for (Cu0:5Zr0:425Ti0:075)99Sn1 and 7 mm for (Cu0:5Zr0:425Ti0:075)98:8Sn0:6Si0:6. The minor addition of Sn or Sn and Si in Cu50Zr42:5Ti7:5 causes an increase in the supercooled liquid region from about 40 K to about 50 K, and in the reduced glass transition temperature from about 0.59 to about 0.60.

Glass Formation and Thermal Stability of Bulk Glassy Cu&ndash;Zr&ndash;Ti&ndash;Sn&ndash;Si Alloys

Glass Formation and Thermal Stability of Bulk Glassy Cu–Zr–Ti–Sn–Si Alloys